{"?xml":{"@version":"1.0"},"edm:RDF":{"@xmlns:dc":"http://purl.org/dc/elements/1.1/","@xmlns:edm":"http://www.europeana.eu/schemas/edm/","@xmlns:wgs84_pos":"http://www.w3.org/2003/01/geo/wgs84_pos","@xmlns:foaf":"http://xmlns.com/foaf/0.1/","@xmlns:rdaGr2":"http://rdvocab.info/ElementsGr2","@xmlns:oai":"http://www.openarchives.org/OAI/2.0/","@xmlns:owl":"http://www.w3.org/2002/07/owl#","@xmlns:rdf":"http://www.w3.org/1999/02/22-rdf-syntax-ns#","@xmlns:ore":"http://www.openarchives.org/ore/terms/","@xmlns:skos":"http://www.w3.org/2004/02/skos/core#","@xmlns:dcterms":"http://purl.org/dc/terms/","edm:WebResource":[{"@rdf:about":"http://www.dlib.si/stream/URN:NBN:SI:doc-R13MY52H/283e8874-5ec4-4639-83e4-17a311e31f71/PDF","dcterms:extent":"4006 KB"},{"@rdf:about":"http://www.dlib.si/stream/URN:NBN:SI:doc-R13MY52H/bd66cc90-7d67-4c69-9287-c6fdcae5a095/TEXT","dcterms:extent":"26 KB"}],"edm:ProvidedCHO":{"@rdf:about":"URN:NBN:SI:doc-R13MY52H","dcterms:issued":"2026","dc:creator":["Birmančević, Dean","Cilenšek, Jena","Kmet, Brigita","Konsago, Sabi William","Malič, Barbara","Žiberna, Katarina"],"dc:format":[{"@xml:lang":"sl","#text":"številka:1"},{"@xml:lang":"sl","#text":"letnik:73"},{"@xml:lang":"sl","#text":"str. 54-61"}],"dc:identifier":["DOI:10.17344/acsi.2025.9607","ISSN:1580-3155","COBISSID_HOST:273144579","URN:URN:NBN:SI:doc-R13MY52H"],"dc:language":"en","dc:publisher":{"@xml:lang":"sl","#text":"Slovensko kemijsko društvo"},"dc:source":{"@xml:lang":"sl","#text":"Acta chimica slovenica"},"dc:subject":[{"@xml:lang":"sl","#text":"kserogeli"},{"@xml:lang":"sl","#text":"Mikrostruktura"},{"@xml:lang":"sl","#text":"tanke plasti"},{"@xml:lang":"sl","#text":"termični razpad"},{"@xml:lang":"en","#text":"thermal decomposition"},{"@xml:lang":"en","#text":"thin films"},{"@xml:lang":"en","#text":"xerogels"}],"dc:title":{"@xml:lang":"sl","#text":"Study of thermal decomposition of (Basub(0.7)Casub(0.3))TiOsub3 and Ba(Zrsub(0.2)Tisub(0.8))Osub3 xerogels and thin films|"},"dc:description":[{"@xml:lang":"sl","#text":"Understanding the thermal decomposition and perovskite phase crystallization enables the design of the desired microstructure of BaTiO3-based thin films prepared by chemical solution deposition. We prepared xerogels from (Ba0.7Ca0.3)TiO3 (BCT) and Ba(Zr0.2Ti0.8)O3 (BZT) coating solutions, as well as BCT and BZT thin films, to investigate their thermal decomposition. The oxycarbonates, formed during the heating of BCT and BZT xerogels, are fully decomposed at 780 °C and 720 °C, respectively. The thermal decomposition of carbonate residues in BCT and BZT thin films is completed at 750 °C and 700 °C, respectively. The approximately 120 nm thick BCT and BZT films annealed at 850 °C crystallize in the perovskite phase"},{"@xml:lang":"sl","#text":"Razumevanje termičnega razpada in kristalizacije perovskitne faze omogoča načrtovanje mikrostrukture tankih plasti na osnovi BaTiO3, pripravljenih s sintezo v raztopini. Iz raztopin prekurzorjev (Ba0.7Ca0.3)TiO3 (BCT) in Ba(Zr0.2Ti0.8)O3 (BZT) smo pripravili ustrezna kserogela s sušenjem pri 200 °C in tanke plasti BCT in BZT z nanašanjem na podlage z metodo vrtenja. Termični razpad organskih skupin v kserogelih poteče preko oksikarbonatnih skupin, ki razpadejo šele po segrevanju pri temperaturah 780 °C (BCT) oziroma 720 °C (BZT). V tankih plasteh BCT in BZT po segrevanju pri 750 °C oziroma 700 °C na zaznamo več sledov ogljikovih faz. Približno 120 nm debele plasti BCT in BZT kristalizirajo v perovskitni fazi po segrevanju pri 850 °C"}],"edm:type":"TEXT","dc:type":[{"@xml:lang":"sl","#text":"znanstveno časopisje"},{"@xml:lang":"en","#text":"journals"},{"@rdf:resource":"http://www.wikidata.org/entity/Q361785"}]},"ore:Aggregation":{"@rdf:about":"http://www.dlib.si/?URN=URN:NBN:SI:doc-R13MY52H","edm:aggregatedCHO":{"@rdf:resource":"URN:NBN:SI:doc-R13MY52H"},"edm:isShownBy":{"@rdf:resource":"http://www.dlib.si/stream/URN:NBN:SI:doc-R13MY52H/283e8874-5ec4-4639-83e4-17a311e31f71/PDF"},"edm:rights":{"@rdf:resource":"http://creativecommons.org/licenses/by/4.0/"},"edm:provider":"Slovenian National E-content Aggregator","edm:intermediateProvider":{"@xml:lang":"en","#text":"National and University Library of Slovenia"},"edm:dataProvider":{"@xml:lang":"sl","#text":"Slovensko kemijsko društvo"},"edm:object":{"@rdf:resource":"http://www.dlib.si/streamdb/URN:NBN:SI:doc-R13MY52H/maxi/edm"},"edm:isShownAt":{"@rdf:resource":"http://www.dlib.si/details/URN:NBN:SI:doc-R13MY52H"}}}}